Copper(I) and Silver(I) π-complexes with allyl derivatives of heterocyclic organic compounds. Synthetic conditions development for new coordination compounds. Crystal structure and properties investigations.

– Karout El H., Shchur Y., Andrushchak A., Sahraoui B., Wielgosz R., Kityk O., Jędryka J., Slyvka Yu., Kityk A. V. Second harmonic generation on crystalline organic nanoclusters under extreme nanoconfinement in functionalized silica–benzil composites // Sci Rep. – 2023. – Vol. 13. – A. 9943. https://www.nature.com/articles/s41598-023-37147-4

– Shchur Ya,  Bendak A., Beltramo G., Andrushchak A.S., Vitusevich S., Pustovyj D., Sahraoui B., Slyvka Yu., Kityk A. V. Nanoarhitectonics of inorganic–organic silica–benzil composites: synthesis, nanocrystal morphology and micro-raman analysis // Nanomaterials. – 2023. – Vol. 13. – A. 1913.  https://www.mdpi.com/2079-4991/13/13/1913

– Koksharova T. 5-Sulfosalicylato Cu(II), Zn(II) and Ni(II) coordination compounds with benzohydrazide: Synthesis, structure and luminescent properties / T. Koksharova, Yu. Slyvka, O. Savchenko, T. Mandzii, S.Smola // J. Mol. Struct. – 2023. – Vol. 1271. – A. 133980. https://doi.org/10.1016/j.molstruc.2022.133980

– Koksharova T. V., Slyvka Y. I., Savchenko O. A., Mandzii T. V. Synthesis and structure of coordination compound of cobalt(II) 5-sulfosalicylate with benzohydrazide // Odesa National University Herald. Chemistry. – 2023. – Vol. 28. – P. 5–14. https://doi.org/10.18524/2304–0947.2023.1(84).277052

– Slyvka Yu. Crystal structure, DFT-study and NLO properties of the novel copper(I) nitrate π,σ-complex based on 1-allyl-3-norbornan-thiourea / Yu. Slyvka, A. A. Fedorchuk, E. Goreshnik, N. Pokhodylo, J. Jedryka, K. Ozga, M.  Mys’kiv // Polyhedron. – 2022. – Vol. 1240. – A. 115545. https://doi.org/10.1016/j.poly.2021.115545

– SlyvkaYu. Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H⁺)}[Cu₈{Acyt(H⁺)}Cl₁₀] with the unusual anionic 1D-coordination polymer /  Slyvka, E. Goreshnik, N. Pokhodylo, D. Morozov, M. Tupychak, M.  Mys’kiv // Polyhedron. – 2022. – Vol. 224. – A. 116022.  https://doi.org/10.1016/j.poly.2022.116022

– Pokhodylo N. T.  Ethyl 5-formyl-1-(pyridin-3-yl)-1H-1,2,3-triazole-4-carboxylate: Synthesis, crystal structure, Hirshfeld surface analysis and DFT calculation / N. T. Pokhodylo, Yu. I. Slyvka, E. A. Goreshnik, M. D. Obushak // Molbank. – 2022. – Vol. 2022., No.1. – P. M1340-10. https://doi.org/10.3390/M1340

– Pavlyuk O. V. 6-Amino-3-(prop-2-en-1-yl)-9H-purin-3-ium tetracopper(I) hexabromide: synthesis and X-ray structure determination / O. V. Pavlyuk, Yu. I. Slyvka, E. A. Goreshnik, M. G. Mys’kiv // Molbank. – 2022. – Vol. 2022. – P. M1401. https://doi.org/10.3390/M1401

– Slyvka Yu. I. 3-Phenyl-4-(prop-2-en-1-yl)-5-[(prop-2-en-1-yl)sulfanyl]-4H-1,2,4-triazole / Yu. I. Slyvka, E. A. Goreshnik, A. M. Fedko, M. G. Mys’kiv // Molbank. – 2022. – Vol. 2022. – P. M1405. https://doi.org/10.3390/M1405

– Slyvka Yu. I. Cu(NH₂SO₃) π-complexes with allyl derivatives of 1,3,4-thiadizoles: synthesis and structural formation through weak interactions / Yu. I. Slyvka, E. A. Goreshnik, N. T. Pokhodylo, M. G. Mys’kiv // J. Chem. Cryst. – 2022. – Vol. 52. – P. 205–213. http://dx.doi.org/10.1007/s10870-021-00906-0

– Pokhodylo N. Synthesis, crystal structure and Hirshfeld surface analysis of N-(4-chlorophenyl)-5-cyclopropyl-1-(4-methoxyphenyl)-1H-1,2,3-triazole-4-carboxamide / N. Pokhodylo, Y. Slyvka and V. Pavlyuk // Acta. Cryst. Sect. E. – 2020. – Vol. E76. – P. 756-760. https://doi.org/10.1107/S2056989020005848

– Yanchak A. π-Coordination compound of copper(І) tetrafluoroborate with N,N-dimethyl-4-[5-(allylsulfanyl)-1H-tetrazol-1-yl]aniline: synthesis and structure characterization / A. Yanchak, H. Andrusiv, Yu. Slyvka, N. Pokhodylo, M. Mys’kiv // Visnyk of the Lviv University. Series Chemistry. – 2020. – No. 61, Pt.1. – P. 135-143.https:/doi.org/10.30970/vch.6101.135

– Fedorchuk A. A. Copper(I) π-coordination compounds with allyl derivatives of disubstituted pseudothiohydantoin: synthesis, structure investigation and nonlinear optical features / A. A. Fedorchuk, Yu. Slyvka, V. Kinzhybalo, I. Kityk, J. Jędryka, M. Mys’kiv // J. Coord. Chem. – 2019. – Vol. 72, No 19-21. – P. 3222-3236.https://doi.org/10.1080/00958972.2019.1687891

– Fedorchuk A. A. An unusual diverse coordination of silver(I) with N-allylthiohydantoin ligand in the presence of benzene- and p-toluenesulfonate anions / A. A. Fedorchuk, Yu. I. Slyvka, V. Kinzhybalo, T. Lis, M. G. Mys’kiv // Inorg. Chim. Acta. – 2019. – Vol. 484. – P. 79-86. https://doi.org/10.1016/j.ica.2018.09.029.

– Hordiichuk O.R. Construction of heterometallic and mixed-valence copper(I/II) chloride π-complexes with 1,2,4-triazole allyl-derivative / O. R. Hordiichuk, Yu. I. Slyvka, V. V. Kinzhybalo, E. A. Goreshnik, T. J. Bednarchuk, O. Bednarchuk, J. Jȩdryka, I. Kityk, M. G. Mys’kiv // Inorg. Chim. Acta. – 2019. – Vol. 495. – P. 119012. https://doi.org/10.1016/j.ica.2019.119012

– Slyvka Yu. The novel copper(I) π,σ-complexes with 1-(aryl)-5-(allylthio)-1H-tetrazoles: Synthesis, structure characterization, DFT-calculation and third-order nonlinear optics / Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, A. A. Fedorchuk, N. Pokhodylo, I. Kityk, M. Mys’kiv // J. Coord. Chem. – 2019. – Vol. 72, No 5-7. – P. 1049–1063. https://doi.org/10.1080/00958972.2019.1580699

– Pokhodylo N. T. Concurrent pathway and unexpected products in the CuAAC reaction of ethyl prop-2-ynyl methylphosphonate with aromatic azides / N. T. Pokhodylo, O. Ya. Shyyka, M. A. Tupychak, Yu. I. Slyvka, M. D. Obushak // Chem. Heteroc. Comp. – 2019. – V. 55 – P. 374-378. https://link.springer.com/article/10.1007/s10593-019-02467-9.

– Slyvka Yu. Synthesis, structural and NLO properties of the novel copper(I) p-toluenesulfonate π-complex with 1-allyloxybenzotriazole / Yu. Slyvka, A. A. Fedorchuk, E. Goreshnik, G. Lakshminarayana, I.V. Kityk, P. Czaja, M. Mys’kiv // Chem. Phys. Lett. – 2018. – Vol. 694. – P. 112-119. https://doi.org/10.1016/j.cplett.2018.01.041

– Fedorchuk A. A. Crystal structure and NLO properties of the novel tetranuclear copper(I) chloride π-complex with 3-allyl-2-(allylimino)-1,3-thiazolidin-4-one / A. A. Fedorchuk, Yu. I. Slyvka, E. A. Goreshnik, I. V. Kityk, P. Czaja, M. G. Mys’kiv // J. Mol. Struct. – 2018. – Vol. 1171. – P. 644-649. https://doi.org/10.1016/j.molstruc.2018.06.017

– Shyyka O. Ya. Understanding the tetrazole ring cleavage reaction with hydrazines: Structural determination and mechanistic insight / O. Ya. Shyyka, N. T. Pokhodylo, Yu. I. Slyvka, E. A. Goreshnik, M. D. Obushak // Tetrahed. Lett. – 2018. Vol. 59. – P. 1112-1115. https://doi.org/10.1016/j.tetlet.2018.02.016

– Slyvka Yu. I. A novel copper(I) sulfamate π-complex based on 5-(allylthio)-1-(3,5-dimethylphenyl)-1H-tetrazole ligand: alternating-current electrochemical crystallization, DFT calculations, structural and NLO properties studies / Yu. I. Slyvka, A. A. Fedorchuk, N. T. Pokhodylo, T. Lis, I. V. Kityk, M. G. Mys’kiv // Polyhedron. – 2018. – Vol. 147. – P. 86-93. https://doi.org/10.1016/j.poly.2018.03.015

– Slyvka Yu. The First copper(I)-olefin complexes bearing a 1,3,4-oxadiazole core: alternating-current electrochemical crystallization, X-ray experiment and DFT study / Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk’yanov, M. Mys’kiv // Polyhedron. – Vol. 133. – (2017). – P. 319-326. https://doi.org/10.1016/j.poly.2017.05.052

– Hordiichuk O. R. Influence of apical ligands on Cu–(C═C) interaction in copper(I) halides (Cl⁻, Br⁻, I⁻) π-complexes with an 1,2,4-triazole allyl-derivative: syntheses, crystal structures and NMR spectroscopy / O. R. Hordiichuk, V. V. Kinzhybalo, E. A. Goreshnik, Y. I. Slyvka, M. S. Krawczyk, M. G. Mys’kiv // J. Organomet. Chem. – Vol. 838. – (2017). – P. 1-8. https://doi.org/10.1016/j.jorganchem.2017.03.022

– Fedorchuk A. А. Unexpected complexation of allylpseudothiohydantoin hydrochlorides towards CuX (X = Cl, NO₃, ClO₄, BF₄, 1/2SiF₆). The first known examples of joint Cu^І (Cl,ClO₄) and Cu^І (Cl,BF₄) π-complexes / A. А. Fedorchuk, V. V. Kinzhybalo, Yu. I. Slyvka, E. A. Goreshnik, T. J. Bednarchuk, T. Lis, M. G. Mys’kiv // J. Coord. Chem. – Vol. 70(5). – 2017. – P. 871-884. http://dx.doi.org/10.1080/00958972.2017.1286012

– Ardan B. Ligand forced dimerization of copper(I)-olefin complexes bearing 1,3,4-thiadiazole core / B. Ardan, V. Kinzhybalo, Yu. Slyvka, O. Shyyka, M. Luk’yanov, T. Lis, M. Mys’kiv // Acta. Cryst. Sect.C – Vol. C73. – 2017. – P. 36-46. https://doi.org/10.1107/S2053229616018751

– Slyvka Yu. I. Crystal structure of an AgClO₄ π-complex with 2-amino-5-allylthio-1,3,4-thiadiazole of the composition [Ag(C₅H₇N₃S₂)(ClO₄)] // J. Struct. Chem. – Vol. 58. – 2017. – P. 356-357. https://doi.org/10.1134/S0022476617020184

– Slyvka Yu. I. Constructing features of crystalline copper(I) benzenesulfonate π-complexes with 2-amino-5-allylthio-1,3,4-thiadiazole // Visnyk of the Lviv Univ. Series Chem. – Vol. 58. – 2017. – P. 172-180.

2000 – 2005 – Student on the Chemistry Faculty of Ivan Franko National University of Lviv. Master thesis “X-ray investigation of copper(I) interaction with 2-butyne-1,4-diol in a presence of alkali metal halide”;
2005 – 2008 – Post-graduate student at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv. The theme of PhD thesis is “Anionic copper(I) halide pi-сomplexes with 2-butyne-1,4-diol: synthesis and crystal structure”.
2018 – 2020 – Doctoral Studies at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv. The theme of Doctoral thesis is “Structural chemistry of copper(I) and silver(I) pi-сomplexes with allyl derivatives of azoles”.

2020 – 2022 – Leader Researcher at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv.

2022 – till now – Associate professor at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv.

Synthesis, structure and nonlinear optical properties of new copper(I) π-complexes based on allyl derivatives of biologically important heterocyclic compounds, 2020-2022(Project Leader);
Controlled synthesis, structure and properties of copper-containing homo- and heterometallic compounds for optoelectronics.

Prize of the President of Ukraine for young scientists (2014)

Prize of the Verkhovna Rada of Ukraine (2023)

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