Copper(I) and Silver(I) π-complexes with allyl derivatives of heterocyclic organic compounds. Synthetic conditions development for new coordination compounds. Crystal structure and properties investigations.

– Pokhodylo N. Synthesis, crystal structure and Hirshfeld surface analysis of N-(4-chlorophenyl)-5-cyclopropyl-1-(4-methoxyphenyl)-1H-1,2,3-triazole-4-carboxamide / N. Pokhodylo, Y. Slyvka and V. Pavlyuk // Acta. Cryst. Sect. E. – 2020. – Vol. E76. – P. 756-760. https://doi.org/10.1107/S2056989020005848

– Yanchak A. π-Coordination compound of copper(І) tetrafluoroborate with N,N-dimethyl-4-[5-(allylsulfanyl)-1H-tetrazol-1-yl]aniline: synthesis and structure characterization / A. Yanchak, H. Andrusiv, Yu. Slyvka, N. Pokhodylo, M. Mys’kiv // Visnyk of the Lviv University. Series Chemistry. – 2020. – No. 61, Pt.1. – P. 135-143.https:/doi.org/10.30970/vch.6101.135

– Fedorchuk A. A. Copper(I) π-coordination compounds with allyl derivatives of disubstituted pseudothiohydantoin: synthesis, structure investigation and nonlinear optical features / A. A. Fedorchuk, Yu. Slyvka, V. Kinzhybalo, I. Kityk, J. Jędryka, M. Mys’kiv // J. Coord. Chem. – 2019. – Vol. 72, No 19-21. – P. 3222-3236.https://doi.org/10.1080/00958972.2019.1687891

– Fedorchuk A. A. An unusual diverse coordination of silver(I) with N-allylthiohydantoin ligand in the presence of benzene- and p-toluenesulfonate anions / A. A. Fedorchuk, Yu. I. Slyvka, V. Kinzhybalo, T. Lis, M. G. Mys’kiv // Inorg. Chim. Acta. – 2019. – Vol. 484. – P. 79-86. https://doi.org/10.1016/j.ica.2018.09.029.

– Hordiichuk O.R. Construction of heterometallic and mixed-valence copper(I/II) chloride π-complexes with 1,2,4-triazole allyl-derivative / O. R. Hordiichuk, Yu. I. Slyvka, V. V. Kinzhybalo, E. A. Goreshnik, T. J. Bednarchuk, O. Bednarchuk, J. Jȩdryka, I. Kityk, M. G. Mys’kiv // Inorg. Chim. Acta. – 2019. – Vol. 495. – P. 119012. https://doi.org/10.1016/j.ica.2019.119012

– Slyvka Yu. The novel copper(I) π,σ-complexes with 1-(aryl)-5-(allylthio)-1H-tetrazoles: Synthesis, structure characterization, DFT-calculation and third-order nonlinear optics / Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, A. A. Fedorchuk, N. Pokhodylo, I. Kityk, M. Mys’kiv // J. Coord. Chem. – 2019. – Vol. 72, No 5-7. – P. 1049–1063. https://doi.org/10.1080/00958972.2019.1580699

– Pokhodylo N. T. Concurrent pathway and unexpected products in the CuAAC reaction of ethyl prop-2-ynyl methylphosphonate with aromatic azides / N. T. Pokhodylo, O. Ya. Shyyka, M. A. Tupychak, Yu. I. Slyvka, M. D. Obushak // Chem. Heteroc. Comp. – 2019. – V. 55 – P. 374-378. https://link.springer.com/article/10.1007/s10593-019-02467-9.

– Slyvka Yu. Synthesis, structural and NLO properties of the novel copper(I) p-toluenesulfonate π-complex with 1-allyloxybenzotriazole / Yu. Slyvka, A. A. Fedorchuk, E. Goreshnik, G. Lakshminarayana, I.V. Kityk, P. Czaja, M. Mys’kiv // Chem. Phys. Lett. – 2018. – Vol. 694. – P. 112-119. https://doi.org/10.1016/j.cplett.2018.01.041

– Fedorchuk A. A. Crystal structure and NLO properties of the novel tetranuclear copper(I) chloride π-complex with 3-allyl-2-(allylimino)-1,3-thiazolidin-4-one / A. A. Fedorchuk, Yu. I. Slyvka, E. A. Goreshnik, I. V. Kityk, P. Czaja, M. G. Mys’kiv // J. Mol. Struct. – 2018. – Vol. 1171. – P. 644-649. https://doi.org/10.1016/j.molstruc.2018.06.017

– Shyyka O. Ya. Understanding the tetrazole ring cleavage reaction with hydrazines: Structural determination and mechanistic insight / O. Ya. Shyyka, N. T. Pokhodylo, Yu. I. Slyvka, E. A. Goreshnik, M. D. Obushak // Tetrahed. Lett. – 2018. Vol. 59. – P. 1112-1115. https://doi.org/10.1016/j.tetlet.2018.02.016

– Slyvka Yu. I. Copper(I) chloride π-complexes with 2,5-bis(allylthio)-1,3,4-thiadiazole: synthesis and structural features / Yu. I. Slyvka, B. R. Ardan, M. G. Mys’kiv // J. Struct. Chem. – 2018. – Vol. 59. – P. 388-394. https://doi.org/10.1134/S0022476618020191

– Slyvka Yu. I. A novel copper(I) sulfamate π-complex based on 5-(allylthio)-1-(3,5-dimethylphenyl)-1H-tetrazole ligand: alternating-current electrochemical crystallization, DFT calculations, structural and NLO properties studies / Yu. I. Slyvka, A. A. Fedorchuk, N. T. Pokhodylo, T. Lis, I. V. Kityk, M. G. Mys’kiv // Polyhedron. – 2018. – Vol. 147. – P. 86-93. https://doi.org/10.1016/j.poly.2018.03.015

– Slyvka Yu. The First copper(I)-olefin complexes bearing a 1,3,4-oxadiazole core: alternating-current electrochemical crystallization, X-ray experiment and DFT study / Yu. Slyvka, E. Goreshnik, G. Veryasov, D. Morozov, M. Luk’yanov, M. Mys’kiv // Polyhedron. – Vol. 133. – (2017). – P. 319-326. https://doi.org/10.1016/j.poly.2017.05.052

– Hordiichuk O. R. Influence of apical ligands on Cu–(C═C) interaction in copper(I) halides (Cl⁻, Br⁻, I⁻) π-complexes with an 1,2,4-triazole allyl-derivative: syntheses, crystal structures and NMR spectroscopy / O. R. Hordiichuk, V. V. Kinzhybalo, E. A. Goreshnik, Y. I. Slyvka, M. S. Krawczyk, M. G. Mys’kiv // J. Organomet. Chem. – Vol. 838. – (2017). – P. 1-8. https://doi.org/10.1016/j.jorganchem.2017.03.022

– Fedorchuk A. А. Unexpected complexation of allylpseudothiohydantoin hydrochlorides towards CuX (X = Cl, NO₃, ClO₄, BF₄, 1/2SiF₆). The first known examples of joint Cu^І (Cl,ClO₄) and Cu^І (Cl,BF₄) π-complexes / A. А. Fedorchuk, V. V. Kinzhybalo, Yu. I. Slyvka, E. A. Goreshnik, T. J. Bednarchuk, T. Lis, M. G. Mys’kiv // J. Coord. Chem. – Vol. 70(5). – 2017. – P. 871-884. http://dx.doi.org/10.1080/00958972.2017.1286012

– Ardan B. Ligand forced dimerization of copper(I)-olefin complexes bearing 1,3,4-thiadiazole core / B. Ardan, V. Kinzhybalo, Yu. Slyvka, O. Shyyka, M. Luk’yanov, T. Lis, M. Mys’kiv // Acta. Cryst. Sect.C – Vol. C73. – 2017. – P. 36-46. https://doi.org/10.1107/S2053229616018751

– Slyvka Yu. I. Crystal structure of an AgClO₄ π-complex with 2-amino-5-allylthio-1,3,4-thiadiazole of the composition [Ag(C₅H₇N₃S₂)(ClO₄)] // J. Struct. Chem. – Vol. 58. – 2017. – P. 356-357. https://doi.org/10.1134/S0022476617020184

– Slyvka Yu. I. Constructing features of crystalline copper(I) benzenesulfonate π-complexes with 2-amino-5-allylthio-1,3,4-thiadiazole // Visnyk of the Lviv Univ. Series Chem. – Vol. 58. – 2017. – P. 172-180.

2000 – 2005 – Student on the Chemistry Faculty of Ivan Franko National University of Lviv. Master thesis “X-ray investigation of copper(I) interaction with 2-butyne-1,4-diol in a presence of alkali metal halide”;
2005 – 2008 – Post-graduate student at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv. The theme of PhD thesis is “Anionic copper(I) halide pi-сomplexes with 2-butyne-1,4-diol: synthesis and crystal structure”.
2018 – 2020 – Doctoral Studies at the Department of Inorganic Chemistry, Ivan Franko National University of Lviv. The theme of Doctoral thesis is “Structural chemistry of copper(I) and silver(I) pi-сomplexes with allyl derivatives of azoles”.

Synthesis, structure and nonlinear optical properties of new copper(I) π-complexes based on allyl derivatives of biologically important heterocyclic compounds, 2020-2022(Project Leader);
Controlled synthesis, structure and properties of copper-containing homo- and heterometallic compounds for optoelectronics.

Prize of the President of Ukraine for young scientists (2014)

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